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Fire-safe polymers : ウィキペディア英語版
Fire-safe polymers
Fire-safe polymers are polymers that are resistant to degradation at high temperatures. There is need for fire-resistant polymers in the construction of small, enclosed spaces such as skyscrapers, boats, and airplane cabins.〔Zhang, H. ''Fire-Safe Polymers and Polymer Composites,'' Federal Aviation Administration technical report; U.S. Department of Transportation: Washington, D.C., 2004.〕 In these tight spaces, ability to escape in the event of a fire is compromised, increasing fire risk. In fact, some studies report that about 20% of victims of airplane crashes are killed not by the crash itself but by ensuing fires.〔Sarkos, C. P. The Effect of Cabin Materials on Aircraft Postcrash Fire Survivability. ''Technical Papers of the Annual Technical Conference'' 1996, ''54'' (3), 3068-3071.〕 Fire-safe polymers also find application as adhesives in aerospace materials,〔Kumar, D.; Gupta, A. D.; Khullar, M. Heat-resistant thermosetting polymers based on a novel tetrakisaminophenoxycyclotriphosphazene. ''J. Polym. Sci. Part A: Polym. Chem.'' 1993, ''31'' (11), 2739-2745. () 〕 insulation for electronics,〔 and in military materials such as canvas tenting.〔Hindersinn, R. R. Historical Aspects of Polymer Fire Retardance. In ''Fire and Polymers – Hazards Identification and Prevention;'' Nelson, G. L., Ed.; American Chemical Society: Washington, D.C., 1990; pp 87-96. ISSN: 0097-6156〕
Some fire-safe polymers naturally exhibit an intrinsic resistance to decomposition, while others are synthesized by incorporating fire-resistant additives and fillers. Current research in developing fire-safe polymers is focused on modifying various properties of the polymers such as ease of ignition, rate of heat release, and the evolution of smoke and toxic gases.〔 Standard methods for testing polymer flammability vary among countries; in the United States common fire tests include the UL 94 small-flame test, the ASTM E 84 Steiner Tunnel, and the ASTM E 622 National Institute of Standards and Technology (NIST) smoke chamber.〔 Research on developing fire-safe polymers with more desirable properties is concentrated at the University of Massachusetts Amherst and at the Federal Aviation Administration where a long-term research program on developing fire-safe polymers was begun in 1995. The Center for UMass/Industry Research on Polymers (CUMIRP) was established in 1980 in Amherst, MA as a concentrated cluster of scientists from both academia and industry for the purpose of polymer science and engineering research.〔
== History ==


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